The unseen photo was taken during their visit to India to promote their 2017 action movie 'xXx: Return of Xander Cage'
The move can escalate its rivalry with Snapchat which it tried to buy in 2013 for $3 billion, tech website CNET reported.
The purchase of the Belarus-based app will add to Facebook's list of creative tools a whole new set of stickers, text on photos and finger doodles.
Facebook said it is acquiring Masquerade -- a startup founded last year that overlays silly and cartoonish images, like an Iron Man helmet or a gorilla face, on people's faces as they shoot video.
A Facebook spokeswoman said Masquerade had "world-class imaging technology for video."
Masquerade's effects are similar to Snapchat's filters. Although Snapchat's audience is smaller than Facebook's, its influence has grown in the past year because of partnerships with media companies, sports leagues and other purveyors of live events.
According to SensorTower, a San Francisco-based app analytics tracker, Masquerade has quickly become a top mobile app and has been downloaded about 12.6 million times since it launched in December.
Masquerade said in a blog post that the startup has "worked hard to make video more fun and engaging by creating filters that enhance and alter your appearance."
"Within Facebook, we're going to be able to reach people at a scale like never before," the post said, adding "This is a scale of audience we never imagined was possible."
The unseen photo was taken during their visit to India to promote their 2017 action movie 'xXx: Return of Xander Cage'
From exploring the Louvre Museum in Abu Dhabi to Easter brunches, there are several things to do in the UAE this weekend
The film is a tense thriller about a group of journalists documenting societal collapse
One song has a reference to the groundbreaking country performer who became the first Black woman to play the 'Grand Ole Opry'
The Oscar-nominated actress is no stranger to big-budget films
In the film, Tabu, Kareena, and Kriti are essaying the roles of daring and mischievous air hostesses
Having effortlessly transitioned into acting, Fouzia's debut film swiftly captured global acclaim, earning accolades at the prestigious Cannes Film Festival
Parag, who reached his 50 off 34 balls, cracked 25 runs with three fours and two sixes off the final over bowled by star South Africa paceman Anrich Nortje